[Ir (bpy) (dfppy)2] PF6
(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
CAS: 864163-80-4
Molecular Formula: C32H22F22IrN4P3
[Ir (bpy) (dfppy)2] PF6 - Names and Identifiers
| Name | (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate |
| Synonyms | (Ir[dFppy]2(bpy))PF6 [Ir (bpy) (dfppy)2] PF6 )pyridine]iridium(III) HexafL (2,2'-Bipyridine)bis[2-(2,4-difL (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate |
| CAS | 864163-80-4 |
[Ir (bpy) (dfppy)2] PF6 - Physico-chemical Properties
| Molecular Formula | C32H22F22IrN4P3 |
| Molar Mass | 1165.6470334 |
| Appearance | powder to crystal |
| Color | Light yellow to Brown |
| Maximum wavelength(λmax) | ['500nm(CH2Cl2)(lit.)'] |
| Storage Condition | Inert atmosphere,Room Temperature |
[Ir (bpy) (dfppy)2] PF6 - Introduction
(2,2 '-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate is a metal-organic complex with the following properties:
1. Appearance: purple red crystal.
2. Thermal stability: It has good thermal stability and is not easy to decompose at high temperatures.
3. solubility: soluble in organic solvents such as methanol, dimethylformamide, insoluble in water.
4. Optical properties: The complex exhibits strong absorption and emission characteristics in the ultraviolet to visible light region, and is suitable for applications such as light-emitting diodes (LEDs) and optoelectronic devices.
In addition, the complex also has the following applications:
1. optoelectronic devices: due to its good emission properties, it can be used to prepare organic light-emitting diodes (OLED), organic electroluminescence (OEL) and other optoelectronic devices.
2. photocatalyst: As a catalyst for photocatalytic reactions, it can be used for photocatalytic oxidation, photolysis of water, carbon dioxide reduction and other reactions.
3. chemical sensors: can be used to prepare chemical sensors for the detection of metal ions, gases and other molecules.
The preparation method of this complex is generally the following steps:
1. First, 2,2 '-bipyridine and 2-(2,4-difluorophenyl) pyridine are reacted with iridium (III) salt to form a complex.
2. Next, by reacting with hexafluorophosphoric acid, a complex in the form of hexafluorophosphate is obtained.
Regarding safety information, this complex has not been extensively studied, so its safety needs to be further evaluated. During handling and use, normal laboratory practices must be followed and contact with eyes, skin and inhalation of dust or vapours must be avoided. In case of accidental contact, flush with plenty of water and seek medical help.
1. Appearance: purple red crystal.
2. Thermal stability: It has good thermal stability and is not easy to decompose at high temperatures.
3. solubility: soluble in organic solvents such as methanol, dimethylformamide, insoluble in water.
4. Optical properties: The complex exhibits strong absorption and emission characteristics in the ultraviolet to visible light region, and is suitable for applications such as light-emitting diodes (LEDs) and optoelectronic devices.
In addition, the complex also has the following applications:
1. optoelectronic devices: due to its good emission properties, it can be used to prepare organic light-emitting diodes (OLED), organic electroluminescence (OEL) and other optoelectronic devices.
2. photocatalyst: As a catalyst for photocatalytic reactions, it can be used for photocatalytic oxidation, photolysis of water, carbon dioxide reduction and other reactions.
3. chemical sensors: can be used to prepare chemical sensors for the detection of metal ions, gases and other molecules.
The preparation method of this complex is generally the following steps:
1. First, 2,2 '-bipyridine and 2-(2,4-difluorophenyl) pyridine are reacted with iridium (III) salt to form a complex.
2. Next, by reacting with hexafluorophosphoric acid, a complex in the form of hexafluorophosphate is obtained.
Regarding safety information, this complex has not been extensively studied, so its safety needs to be further evaluated. During handling and use, normal laboratory practices must be followed and contact with eyes, skin and inhalation of dust or vapours must be avoided. In case of accidental contact, flush with plenty of water and seek medical help.
Last Update：2024-04-09 21:04:16
![[Ir (bpy) (dfppy)2] PF6](http://res.chembk.com/assets/images/structure/864163-80-4.gif)